In one of its most
common forms, vinegar has been used as a preservative since ancient
times.
Vinegar
can be made from any liquid that is capable of being converted into
alcohol in a two stage process. During fermentation the sugar in the
liquid is converted into alcohol and carbon dioxide gas by the actions
of yeast enzymes. Then, the alcohol combines with atmospheric oxygen
by the action of the Acetobacter bacteria, forming acetic acid and water.
It
is because of the variety of source materials, and the differing organic
acids and esters derived from that source material which are also present,
that are responsible for the different flavours and aromas of vinegar,
for example, grapes - wine vinegar, apples - cider vinegar, malted barley
or oats - malt vinegar.
In
addition to the method for producing vinegar, large amounts of acetic
acid are prepared synthetically either by acetylene being hydrated to
acetaldehyde, which is then oxidized or by a process using methanol,
from gas or oil, and carbon monoxide.
In
foods it is used for its antibacterial properties, as an acidity stabiliser,
diluting colourings, as a flavouring agent and for inhibiting mould
growth in bread. In brewing it is used to reduce excess losses of carbohydrate
from the germinated barley and to compensate for production variations,
so producing a consistent quality beer.
It
can be found in beer, bread, cheese, chutney, horseradish cream, pickles,
salad cream, brown sauce, fruit sauce, mint sauce and jelly and tinned
baby food, sardines and tomatoes.
Occurring
naturally in body fluids and plant juices acetic acid, also called ethanoic
acid, is the most important of the carboxylic acids. It is an important
metabolic intermediate being involved in fatty acid and carbohydrate
metabolism.